Example 2.13:  Calculate Joule-Thompson coefficient of hydrogen when it is expanded from 20 bar to 5 bar at 100 °K.  Critical pressure and critical temperature are 12.5 atm and 23.25 °K, respectively.

 

Solution 

$                 Initial enthalpy, h (20 bar and 100 °K) = 1546 J/g.

$                 Final temperature (5 bar and 1546 J/g) = 98.03 °K.

 

$                 Joules-Thompson coefficient μj (Equation 2.43):